Publications

  1. M. J. Alonso-Navarro, S. Franco*, F. Suárez-Blas, R. Andreu, J. Orduna, M. M. Ramos, J. L. Segura*. Core and end-capped engineering as a powerful tool in the search of long-term high-performance dye-sensitized solar cells. ChemSusChem 2025, 18, e202501564 https://doi.org/10.1002/cssc.202501564
  2. A. Ansón-Casaos*, A.M. Benito, W.K. Maser, J. Orduna, B. Villacampa, M.J. Blesa*. Hybrids of Deep HOMO Organic Cyanoacrylic Acid Dyes and Graphene Nanomaterials for Water Splitting Photoanodes. Materials 2025, 18, 463.  https://doi.org/10.3390/ma18020463
  3. I. Morel-Moreno, R. Ramírez-Bon, B. Villacampa, C. Carrasco, M. Valdés, C. Rodríguez. Establishing the hierarchy of growth-driven properties in CdS thin films and their role in CdS/PbS solar cell performance. J. Alloids and Compounds, 2025, 1039, 183225. https://doi.org/10.1016/j.jallcom.2025.183225
  4. Daniel Joven-Sancho, Miguel Baya, Antonio Martín, Jesús Orduna, Babil Menjón. The CF3 Group as a Synthon of the CF+ Unit in Palladium Chemistry. Angew. Chem. Int. Ed., 2024,  63, e202403108. https://doi.org/10.1002/anie.202403108
  5. R. Royo, J. G. Sánchez, W. Li, E. Martínez-Ferrero, E. Palomares, R. Andreu, S. Franco. Novel Spiro-Core Dopant-Free Hole Transporting Material for Planar Inverted Perovskite Solar Cells. Nanomaterials 2023, 13, 2042. https://doi.org/10.3390/nano13142042.
  6. : L. Pizarro-Castillo, A.-C. Mera, G. Cabello-Guzmán, C. Bernal, M. Bizarro, C. Carrasco, M. J. Blesa, C.A. Rodríguez. The effect of sintering temperature on the properties of the BiOCl films for potential application in DSSC. : Ceramics International 2023,  49, 16305-16313.
     https://doi.org/10.1016/j.ceramint.2023.01.229.
  7. I. Duerto, C. Carrera, D. Barrios, A.-M. Benito, W.-K. Maser, B. Villacampa, E. García-Bordejé, M. J. Blesa. Metal-Free Counter Electrodes for DSSCs Based on Nitrogen-Doped Reduced Graphene Oxide Materials. Colorants 2023, 2, 443–452. https://doi.org/10.3390/colorants2020020.
  8. A. Ansón-Casaos, C. Martínez-Barón, S. Angoy-Benabarre, J. Hernández-Ferrer, A.M. Benito, W.K. Maser, M.J. Blesa, Stability of a pyrimidine-based dye-sensitized TiO2 photoanode in sacrificial electrolytes, J. Electroanal. Chem., 2023, 929, 117114.  https://doi.org/10.1016/j.jelechem.2022.117114
  9. R. Royo, P. Mainik, C. Benitez-Martin, R. Andreu, E. Blasco, F. Najera, B. Villacampa. Highly efficient photoninitiators based on 4H-pyranylidene derivatives for two-photon laser printing. Adv. Mater. Technol. 2023, 2300571. https://doi.org/10.1002/admt.202300571.
  10. Pérez-Bitrián, A.; Álvarez, S.; Baya, M.; Echeverría, J.; Martín, A.; Orduna, J.; Menjón. B. “Terminal Au–N and Au–O Units in Organometallic Frames”. Chem. Eur. J. 2023, 29, e202203181. https://doi.org/10.1002/chem.202203181
  11. Duerto, I.; Sarasa, S.; Barrios, D.; Orduna, J.; Villacampa, B.; Blesa, M.-J. “Enhancing the temporal stability of DSSCs with novel vinylpyrimidine anchoring and accepting group”. Dyes Pigm. 2022, 203, 110310. https://doi.org/10.1016/j.dyepig.2022.110310
  12. Royo, R.; Domínguez-Celorrio, A.; Franco, S.; Andreu, R.; Orduna, J. “Pyranylidene/Trifluoromethylbenzoic acid-based chromophores for Dye-Sensitized Solar Cells”. Dyes Pigm. 2022, 206, 110566. https://doi.org/10.1016/j.dyepig.2022.110566
  13. V. Tejeda-Orusco, R. Andreu*, J. Orduna, B. Villacampa, S. Franco, A. Civera. “Twisted one-dimensional charge transfer and related Y-shaped chromophores featuring a 4H-pyranylidene donor: synthesis and optical properties”. J. Org. Chem. 2021, 86, 3152-3163. https://dx.doi.org/10.1021/acs.joc.0c02438
  14. S. Aina, B. Villacampa, M. Bernechea. “Earth-abundant non-toxic perovskite nanocrystals for solution processed solar cells”. Mater. Adv. 2021, 2, 4140-4151. https://doi.org/10.1039/D1MA00245G
  15. S. Gámez-Valenzuela, D. Neusser, C. Benítez-Martín, F. Najera, J. A. Guadix, C. Moreno-Yruela, B. Villacampa, R. Ponce Ortiz, S. Ludwigs, R. Andreu*, M. C. Ruiz Delgado*. “V-shaped Pyranylidene/Triphenylamine-based Chromophores with Enhanced Photophysical, Electrochemical and Nonlinear Optical Properties”. Mater. Adv. 2021, 2, 4255-4263. https://doi.org/10.1039/D1MA00415H
  16. J. M. González-Domínguez, A. Baigorri, M. Á. Álvarez-Sánchez, E. Colom, B. Villacampa, A. Ansón-Casaos, E. García-Bordejé, A. M. Benito, W. K. Maser. “Waterborne Graphene- and Nanocellulose-Based Inks for Functional Conductive Films and 3D Structures”. Nanomaterials 2021, 11, 1435. https://doi.org/10.3390/nano11061435
  17. C. Jarne, L. Membrado, M. Saviron, J. Vela, J. Orduna, R. Garriga, J. Galban, V. L. Cebolla. “Globotriaosylceramide-Related Biomarkersof Fabry Disease Identified in Plasma by High-PerformanceThin-Layer Chromatography – Densitometry- Mass Spectrometry” J. Chrom. A  2021, 1638, 461895. https://doi.org/10.1016/j.chroma.2021.461895
  18. B. Menjón, D. Joven-Sancho, M. Baya, L. R. Falvello, A. Martín, J. Orduna. “Stability of AgIII towards Halides in Organosilver(III) Complexes”. Chem. Eur. J.2021, 27, 12796-12806. https://doi.org/10.1002/chem.202101859
  19. D. Joven-Sancho, M. Baya, A. Martín, J. Orduna, B. Menjón. “The First Five-coordinate Compound with Inverted Ligand Field: An Unprecedented Geometry for Silver(III)”. Angew. Chem. Int. Ed2021, 60, 26545–26549. https://doi.org/10.1002/anie.202112449
  20. Sánchez J. R., Nova V, Bachiller C, Villacampa B., de la Rua A, Kronberger R, Peñaranda-Foix F., Boria V. E. “Characterization of Nematic Liquid Crystal at Microwave Frequencies Using Split-Cylinder Resonator Method” IEEE Trans. Microw. Theory Techn. 202067, 2812-2820. 10.1109/TMTT.2019.2916790
  21. Menjón, B.; Joven-Sancho, D.;  Baya, M.; Martín, A.; Orduna, J. The First Organosilver(III) Fluo-ride, [PPh4][(CF3)3AgF]. Chem. Eur. J., 2020, 26, 4471-4475. https://doi.org/10.1002/chem.201905771
  22. I. Duerto, M. García-Palacín, D. Barrios, J. Garín, J. Orduna, B. Villacampa, M.-J. Blesa, A novel σ-linkage to dianchor dyes for efficient dyes sensitized solar cells: 3-methyl-1,1-cyclohexane, Dyes Pigm.2020, 173, 107945. https://doi.org/10.1016/j.dyepig.2019.107945
  23. I. Duerto, D. Barrios, J. Garín, J. Orduna, B. Villacampa, M.-J. Blesa, “Difunctionalized dyes for DSSCs based on two different scaffolds: p-tert-butylcalix[4]arene or isophthalic acid”, Dyes Pigm., 2020, 182, 2020, 108530. https://doi.org/10.1016/j.dyepig.2020.108530
  24. Rodríguez, C. A.; Delgadillo, A; Núñez, J.; Cabello-Guzmán, G.; Mera, A.C.; Delplancke, M. P.; Villacampa, B.; Carrasco, C. “Effect of supporting electrolyte concentration on one-step electrodeposited CuInS2 films for ZnS/CuInS2 solar cell applications”. J. Solid State Electrochem. 2020, 24, 1405-1414.  https://doi.org/10.1007/s10008-020-04622-1
  25. Rothe C., Neusser D., Hoppe N., Dirnberger K., Vogel W., Gámez-Valenzuela S.,López Navarrete J.T.; Villacampa B., Berroth M., Ruiz Delgado M.C., Ludwigs S. “Push–pull thiophene chromophores for electro-optic applications: from 1D linear to β-branched structures”. Phys. Chem. Chem. Phys2020, 22, 2283-2294. https://doi.org/10.1039/C9CP05640H
  26. V. Tejeda-Orusco, M- Blais, C. Cabanetos, P. Blanchard, R. Andreu, S. Franco, J. Orduna, B.E. Diosdado. 4H-pyranylidene-based small push-pull chromophores: Synthesis, structure, electronic properties and photovoltaic evaluation. Dyes Pigm. 2020, 178, 108357. https://doi.org/10.1016/j.dyepig.2020.108357
  27. Santidrián A., Sanahuja O., Villacampa B., Díez J.L., Benito A.M., Maser W.K., Muñoz, E., Ansón-Casaos, A. Chemical Postdeposition Treatments to Improve the Adhesion of Carbon Nanotube Films on Plastic Substrates. ACS Omega 2019, 4, 2804−2811. https://doi.org/10.1021/acsomega.8b03475
  28. Hernández-Ferrer J., Ansón-Casaos A., Víctor-Román S., Sanahuja-Parejo O, Martínez M.T., Villacampa B., Benito A.M., Maser W.K. Photoactivity improvement of TiO2 electrodes by thin hole transport layers of reduced graphene oxide. Electrochimica Acta2019, 298,  279-287. https://doi.org/10.1016/j.electacta.2018.12.085
  29. J.M. Andrés-Castán, R. Andreu, B. Villacampa, J. Orduna, S. Franco*. 4H-pyranylidene organic dyes for dye-sensitized solar cells: Twisted structures towards enhanced power conversion efficiencies. Solar Energy 2019193, 74-84. https://doi.org/10.1016/j.solener.2019.09.028
  30. E. Colom, J.M. Andrés-Castán, D. Barrios, I. Duerto, S. Franco, J. Garín, J. Orduna, B. Villacampa, M.J. Blesa*. Modification of the electronic properties of the pi-spacer of chromophores linked to calix [4] arene platform for DSSCs applications. Dyes Pigm. 2019164, 43-53. https://doi.org/10.1016/j.dyepig.2018.12.066
  31. Fayos, O.; Ochoa-Alejo, N.; Martínez de la Vega, O.; Savirón, M.; Orduna, J.; Mallor, C.; Barbero, G. F.; Garcés-Claver, A. Assessment of Capsaicinoid and Capsinoid Accumulation Patterns during Fruit Development in Three Chili Pepper Genotypes (Capsicum spp.) Carrying Pun1 and pAMT Al-leles Related to Pungency. J. Agric. Food Chem., 2019, 67, 12219−1222. https://doi.org/10.1021/acs.jafc.9b05332
  32. Baya, M.; Joven-Sancho, D.; Alonso, P. J.; Orduna, J.; Menjón, B. M–C Bond Homolysis in Coin-age-Metal [M(CF₃)₄]⁻ Derivatives. Angew. Chem. Int. Ed. Eng., 2019, 131, 10059-10063. https://doi.org/10.1002/anie.201903496
  33. Lapieza, M. P.; Jungas, C.; Savirón, M.; Jarne, C.; Membrado, L.; Vela, J.; Orduna, J.; Garriga, R.;  Galbán, J.; Cebolla, V. L. HPTLC coupled to ESI-Tandem MS for identifying phospholipids associat-ed to membrane proteins in photosynthetic purple bacteria. J. Liq. Chromatogr. Relat. Technol. 2019, 42, 1-8. https://doi.org/10.1080/10826076.2018.1561465
  34. Fayos, O.; Savirón, M.; Orduna, J.; Barbero, G. F.; Mallor, C.; Garcés-Claver, A. Quantitation of Capsiate and Dihydrocapsiate and Tentative Identification of Minor Capsinoids in Pepper Fruits (Cap-sicum spp.) by HPLC-ESI-MS/MS(QTOF). Food Chemistry, 2019, 270, 264-272. https://doi.org/10.1016/j.foodchem.2018.07.112
  35. C. Bottecchia, R. Martín, I. Abdiaj, E. Crovini, J. Alcazar, J. Orduna, M. J. Blesa, J. R. Carrillo, P. Prieto, T. Noël, De novo Design of Organic Photocatalysts: Bithiophene Derivatives for the Visible-light Induced C−H Functionalization of Heteroarenes. Adv. Synth. Catal. 2019361, 945.   https://doi.org/10.1002/adsc.201801571
  36. CB. Cooper, EJ. Beard, A. Vázquez-Mayagoitia, L. Stan, GBG. Stenning, DW. Nye, JA. Vigil, T. Tomar, JW. Jia, GB. Bodedla, S. Chem, L. Gallego, S. Franco, A. Carella, KRJ. Thomas, S. Xue, XJ. Zhu, JM. Cole*. Design-to-Device Approach Affords Panchromatic Co-Sensitized Solar Cells. Advanced Energy Materials 20199, 1802820. https://doi.org/10.1002/aenm.201802820
  37. B. Marco, N. Martínez de Baroja, J.M. Andrés-Castán, S. Franco, R. Andreu. B. Villacampa, J. Orduna, J. Garín. Pyranylidene/thienothiophene-based organic sensitizers for dye-sensitized solar cells. Dyes Pigments 2019, 161, 205-213. https://doi.org/10.1016/j.dyepig.2018.09.035
  38. Pérez-Bitrián, A.; Baya, M.; Casas, J. M.; Martín, A.; Menjón, B.; Orduna, J. An Organogold(III) Difluoride with a trans Arrangement. Angew. Chem. Int. Ed. Eng., 2018, 130, 6627 –6631. https://doi.org/10.1002/anie.2018023
  39. Jarne, C.; Lapieza, M. P.; Membrado, L.; Cebolla, V. L.; Savirón, M.; Orduna, J.; Galbán, J.; Mor-lock, G. E. High-Performance Thin-Layer Chromatography Coupled with Electrospray Ionization Tandem Mass Spectrometry for Identifying Neutral Lipids and Sphingolipids in Complex Samples. J. AOAC Int., 2018, 101, 1993-2000. https://doi.org/10.5740/jaoacint.17-0329
  40. Fayos, O.; Barbero, G. F.; Savirón, M.; Orduna, J.; Durán, A. G.; Palma, M.; Molinillo, J. M. G.; Macías, F. A.; Barroso, C. G.; Mallor, C.; Garcés-Claver, A. Synthesis of (±)-3,4-dimethoxybenzyl-4-methyloctanoate as a novel internal standard for capsinoid determination by HPLC-ESI-MS/MS(QTOF). Open Chem., 2018, 16, 87–94. https://doi.org/10.1515/chem-2018-0007
  41. Baya, M.; Pérez-Bitrián, A.; Martínez-Salvador, S.; Martín, A.; Casas, J. M.; Menjón, B.; Orduna, J. Gold(II) Trihalide Complexes from Organogold(III) Precursors. Chem. Eur. J., 2018, 24, 1514-1518. https://doi.org/10.1002/chem.201705509
  42. I. Duerto, E. Colom, J.M. Andrés-Castán, S. Franco, J. Garín, J. Orduna. B. Villacampa, M.J. Blesa. DSSCs based on aniline derivatives functionalized with a tert-butyldimethylsilyl group and the effect of the pi-spacer. Dyes Pigm. 2018, 148, 61-71. https://doi.org/10.1016/j.dyepig.2017.07.063
  43. J. Romero, J. Barberá, M.-J. Blesa, A. Concellón, P. Romero, J. L. Serrano, M. Marcos, Liquid Crystal Organization of Calix[4]arene-Appended Schiff Bases and Recognition towards Zn2+. ChemistrySelect 2017, 2, 101. https://doi.org/10.1002/slct.201601826
  44. Pérez-Bitrián, A.; Martínez-Salvador, S.; Baya, M.; Casas, J. M.; Martín, A.; Menjón, B.; Orduna, J. Anionic Derivatives of Perfluorinated Trimethylgold. Chem. Eur. J., 2017, 23, 6919-6929. https://doi.org/10.1002/chem.201700927
  45. Baya, M.; Pérez-Bitrián, A.; Martínez-Salvador, S.; Casas, J. M.; Menjón, B.; Orduna, J. Gold(I) Fluorohalides: Theory and Experiment. Chem. Eur. J., 2017, 23, 1512-1515. https://doi.org/10.1002/chem.201605655
  46. Hoppe N., Rothe C., Celik A., Rosa M.F., Vogel W., Widmann D., Rathgeber L., Ruiz-Delgado M.C., Villacampa B., Ludwigs S., Berroth M.. Single waveguide silicon-organic hybrid modulator. Adv. Radio Sci., 2017, 15, 1–7. https://ars.copernicus.org/articles/15/141/2017/
  47. I. Torres, A. Díaz-Ortiz, L. Sánchez, J. Orduna, M.J. Blesa, J.R. Carrillo, P. Prieto. “Tunable emission in aggregated T-Shaped 2H-Benzo[d][1,2,3]triazoles with waveguide behaviour”, Dyes Pigm., 2017, 142, 212-225. https://doi.org/10.1016/j.dyepig.2017.02.048
  48. E. Colom, J.-M. Andrés-Castán, S. Franco, J. Garín, J.-F. Montoya, J. Orduna, B. Villacampa, M.J. Blesa, Multichromophoric sensitizers based on calix[4]arene scaffold and 4H-pyranylidene moiety for DSSCs application, Dyes Pigm., 2017, 136, 505-514. https://doi.org/10.1016/j.dyepig.2016.08.067
  49. C. Jarne, V. L. Cebolla, L. Membrado; J. Galbán; M. Savirón; J. Orduna; R. Garriga. Separation and profiling of monoglycerides in biodiesel using a hyphenated technique based on high-performance thin-layer chromatography. Fuel, 2016, 177, 244–250. https://doi.org/10.1016/j.fuel.2016.03.011
  50. A. Belén Marco, Fátima Aparicio, Lara Faour, Konstantinos Iliopoulos, Yohann Morille, Magali Allain, Santiago Franco, Raquel Andreu, Bouchta Sahraoui, Denis Gindre, David Canevet and Marc Sallé. Promoting Spontaneous Second Harmonic Generation through Organogelation. J. Am. Chem. Soc. 2016, 138, 9025-9028. https://doi.org/10.1021/jacs.6b04554
  51. I. Torres, J. R. Carrillo, A. Díaz-Ortiz, R. Martín, M. V. Gómez, L. Stegemann, C. A. Strassert, J. Orduna, J. Buendía, E. E. Greciano, J. S. Valera, E. Matesanz, L. Sánchez, P. Prieto. Self-assembly of T-shape 2H-benzo[d][1,2,3]-triazoles. Optical waveguide and photophysicalproperties. RSC Adv., 2016, 6, 36544–36553. https://doi.org/10.1039/C6RA02473D
  52. Martínez-Abadía M., Robles-Hernández B., Villacampa B., de la Fuente M. R., Giménez R., Ros M.B. Cyanostilbene bent-core molecules: a route to functional materials. J. Mater Chem. C. 2015, 3, 3038-48. https://doi.org/10.1039/C5TC00201J
  53. J. M. Andrés-Castán, S. Franco, B. Villacampa, J. Orduna, R. Pérez-Tejada. New efficient Tert-butyldiphenyl-4H-pyranylidene sensitizers for DSSC. RSC Adv., 2015, 5, 106706–106709. https://doi.org/10.1039/C5RA23339A
  54. Moreno-Yruela, Carlos; Garín, Javier; Orduna, Jesús; Franco, Santiago; Quintero, Estefanía; López Navarrete, Juan T.; Diosdado, Beatriz; Villacampa, Belén; Casado, Juan; Andreu, Raquel. D−π–A Compounds with Tunable Intramolecular Charge Transfer Achieved by Incorporation of Butenolide Nitriles as Acceptor MoietiesJ. Org. Chem. 2015, 80, 12115-12128. https://doi.org/10.1021/acs.joc.5b02051
  55. M. Castillo-Vallés, J. M. Andrés-Castán, J. Garín, J. Orduna, B. Villacampa, S. Franco, M. J. Blesa. Dye-Sensitized-Solar-Cells based on calix[4]arene scaffold. RSC Advances, 2015, 5, 90667–90670. https://doi.org/10.1039/C5RA15184H
  56. R. Pérez-Tejada, N. Martínez de Baroja, S. Franco, L. Pellejà, J. Orduna, R. Andreu, J. Garín. Organic sensitizers bearing a trialkylsilylether group for liquid dye sensitized solar cells. Dyes Pigm., 2015, 123, 293-303. https://doi.org/10.1016/j.dyepig.2015.07.026
  57. A. Abate, R. Pérez Tejada, H. J. Snaith, S. Franco, J. Orduna. Phosphonic anchoring groups in organic dyes for solid-state solar cells. PhysChemChemPhys. 2015, 17, 18780-18789. https://doi.org/10.1039/C5CP02671G
  58. García-Rodriguez, A.; Rodríguez, A. M.; Prieto, P.; Andreu, R.; Merino, S.; Rodríguez-López, J., Swivel-Cruciform Stilbenes Based on Bithiophene. Eur. J. Org. Chem. 2015, 2394-2404. https://doi.org/10.1002/ejoc.201500071
  59. Marco, A. B.; Martínez de Baroja, N.; Franco, S.; Garín, J.; Orduna, J.; Villacampa, B.; Revuelto, A.; Andreu, R. Dithienopyrrole as a Rigid Alternative to the Bithiophene π Relay in Chromophores with Second-Order Nonlinear Optical Properties. Chem. Asian J. 2015, 10, 188-197. https://doi.org/10.1002/asia.201402870
  60. González-Laínez, M.; Jiménez-Ruiz, M. T.; Martínez de Baroja, N.; Garín, J.; Orduna, J.; Villacampa, B.; Blesa, M. J., Using functionalized nonlinear optical chromophores to prepare NLO-active polycarbonate films. Dyes Pigm. 2015, 119, 30-40. https://doi.org/10.1016/j.dyepig.2015.02.026
  61. Domínguez, A.; Jarne, C.; Cebolla, V.; Galbán, J.; Savirón, M.; Orduna, J.; Membrado, L.; Lapieza, M.-P.; Romero, E.; Sanz Vicente, I.; de Marcos, S.; Garriga, R. A Hyphenated Technique based on High-Performance Thin Layer Chromatography for Determining Neutral Sphingolipids: A Proof of Concept. Chromatography 2015, 2, 167-187. https://doi.org/10.3390/chromatography2020167
  62. Gomez-Torres, M. J.; Garcia, E. M.; Guerrero, J.; Medina, S.; Izquierdo-Rico, M. J.; Gil-Izquierdo, A.; Orduna, J.; Saviron, M.; Ten, J.; Bernabeu, R.; De Juan, J.; Aviles, M. Metabolites Involved in cellular communication among human cumulus-oocyte-complex and sperm during in vitri fertilization. Reprod. Biol. Endocrinol., 2015, 13:123. https://doi.org/10.1186/s12958-015-0118-9
  63. Marco, A. B.; Mayorga Burrezo, P.; Mosteo, L.; Franco, S.; Garín, J.; Orduna, J.; Diosdado, B. E.; Villacampa, B.; López Navarrete, J. T.; Casado, J.; Andreu, R., Polarization, second-order nonlinear optical properties and electrochromism in 4H-pyranylidene chromophores with a quinoid/aromatic thiophene ring bridge. RSC Adv. 2015, 5, 231-242. https://doi.org/10.1039/C4RA12791A
  64. Pérez-Tejada, R.; Pellejà, L.; Palomares, E.; Franco, S.; Orduna, J.; Garín, J.; Andreu, R., Novel 4H-pyranylidene organic dyes for dye-sensitized solar cells: Effect of different heteroaromatic rings on the photovoltaic properties. Org. Electron. 2014, 15, 3237-3250. https://doi.org/10.1016/j.orgel.2014.09.003
  65. Martínez de Baroja, N.; Franco, S.; Garín, J.; Orduna, J.; Villacampa, B.; Borja, P.; Alicante, R., Synthesis, characterization, and optical properties of novel 1,3-dithiole donor-based chromophores. RSC Adv. 2013, 3, 2953-2962. https://doi.org/10.1039/C2RA23235A
  66. Marco, A. B.; Andreu, R.; Franco, S.; Garín, J.; Orduna, J.; Villacampa, B.; Diosdado, B. E.; López Navarrete, J. T.; Casado, J., Push-pull systems bearing a quinoid/aromatic thieno[3,2-b]thiophene moiety: synthesis, ground state polarization and second-order nonlinear properties. Org. Biomol. Chem. 2013, 11, 6338-6349. https://doi.org/10.1039/C3OB41278D
  67. Marco, A. B.; Andreu, R.; Franco, S.; Garín, J.; Orduna, J.; Villacampa, B.; Alicante, R., Efficient second-order nonlinear optical chromophores based on dithienothiophene and thienothiophene bridges. Tetrahedron 2013, 69, 3919-3926. https://doi.org/10.1016/j.tet.2013.03.027
  68. Zafra, J. L.; Andreu, R.; Galán, E.; Orduna, J.; Garín, J.; Martín Ortiz, J.; López Navarrete, J. T.; Casado, J., Interpretation of the infrared and Raman spectra of zwitterionic push-pull dyes based on quinoidal thiazole. J. Mol. Struct. 2013, 1044, 55-60. https://doi.org/10.1016/j.molstruc.2012.11.045
  69. Coe, B. J.; Foxon, S. P.; Helliwell, M.; Rusanova, D.; Brunschwig, B. S.; Clays, K.; Depotter, G.; Nyk, M.; Samoc, M.; Wawrzynczyk, D.; Garín, J.; Orduna, J., Heptametallic, octupolar nonlinear optical chromophores with six ferrocenyl substituents. Chem. Eur. J. 2013, 19, 6613-6629. https://doi.org/10.1002/chem.201204453
  70. Alicante R., Cases R., Villacampa B., Blasco, E. Matrix Order Influence on the Nonlinear Optical Properties of Dispersed Chromophore-Azopolymer Systems. Macrom. Chem. Phys, 2012, 213, 776-783. https://doi.org/10.1002/macp.201100649
  71. Martínez de Baroja, N.; Garín, J.; Orduna, J.; Andreu, R.; Blesa, M. J.; Villacampa, B.; Alicante, R.; Franco, S., Synthesis, Characterization, and Optical Properties of 4H-Pyran-4-ylidene Donor-Based Chromophores: The Relevance of the Location of a Thiophene Ring in the Spacer. J. Org. Chem. 2012, 77, 4634-4644. https://doi.org/10.1021/jo300373m
  72. Galán, E.; Andreu, R.; Garín, J.; Orduna, J.; Villacampa, B.; Diosdado, B. E., Cycloaddition reactions of polyenic donor-π-acceptor systems with an electron-rich alkyne: access to new chromophores with second-order optical nonlinearities. Org. Biomol. Chem. 2012, 10, 8684-8691. https://doi.org/10.1039/C2OB26515J
  73. Galán, E.; Andreu, R.; Garín, J.; Mosteo, L.; Orduna, J.; Villacampa, B.; Diosdado, B. E., Influence of thiazole regioisomerism on second-order nonlinear optical chromophores. Tetrahedron 2012, 68, 6427-6437. https://doi.org/10.1016/j.tet.2012.05.123
  74. Franco, S.; Garín, J.; Martínez de Baroja, N.; Pérez-Tejada, R.; Orduna, J.; Yu, Y.; Lira-Cantú, M., New D-π-A-Conjugated Organic Sensitizers Based on 4H-Pyran-4-ylidene Donors for Highly Efficient Dye-Sensitized Solar Cells. Org. Lett. 2012, 14, 752-755. https://doi.org/10.1021/ol203298r
  75. Andreu, R.; Franco, S.; Garín, J.; Romero, J.; Villacampa, B.; Blesa, M. J.; Orduna, J., Multichromophoric Calix[4]arenes: Effect of Interchromophore Distances on Linear and Nonlinear Optical Properties. ChemPhysChem 2012, 13, 3204-3209. https://doi.org/10.1002/cphc.201200203
  76. Rodríguez-Celma, J.; Vázquez-Reina, S.; Orduna, J.; Abadía, A.; Abadía, J.; Alvárez-Fernández, A.; López-Millán, A.-F., Characterization of Flavins in Roots of Fe-Deficient Strategy I Plants, with a Focus on Medicago truncatula. Plant Cell Physiol. 2011, 52, 2173-2189. https://doi.org/10.1093/pcp/pcr149
  77. González, S. R.; Orduna, J.; Alicante, R.; Villacampa, B.; McGee, K. A.; Pina, J.; Seixas de Melo, J.; Schwaderer, K. M.; Johnson, J. C.; Blackorbay, B. A.; Hansmeier, J. J.; Bolton, V. F.; Helland, T. J.; Edlund, B. A.; Pappenfus, T. M.; López Navarrete, J. T.; Casado, J., Understanding Optoelectronic Properties of Cyano-Terminated Oligothiophenes in the Context of Intramolecular Charge Transfer. J. Phys. Chem. B 2011, 115, 10573-10585. https://doi.org/10.1021/jp2070375
  78. Andreu, R.; Galán, E.; Orduna, J.; Villacampa, B.; Alicante, R.; López Navarrete, J. T.; Casado, J.; Garín, J., Aromatic/Proaromatic Donors in 2-Dicyanomethylenethiazole Merocyanines: From Neutral to Strongly Zwitterionic Nonlinear Optical Chromophores. Chem. Eur. J. 2011, 17, 826-838. https://doi.org/10.1002/chem.201002158
  79. Alicante R., Cases R., Villacampa B., Oriol L. Tailoring Linear and Nonlinear Optical Properties of a Side-Chain Liquid Crystalline Azo-Polymethacrylate. Macromol. Chem. Phys. 2010, 211, 2218–2225. https://doi.org/10.1002/macp.201000238
  80. Latorre S., Moreira I. P. R., Villacampa B., Julià Ll., Velasco D., Bofill J.M., López-Calahorra, F. Differential Behavior of Amino–Imino Constitutional Isomers in Nonlinear Optical Processes. ChemPhysChem, 2010, 11, 912–919. https://doi.org/10.1002/cphc.200900616
  81. Pintre I. C., Serrano J.L., Ros M. B., Martínez-Perdiguero J., Alonso I., Ortega J., Folcia C.L., Etxebarria J., Alicante R., Villacampa B. Bent-core liquid crystals in a route to efficient organic nonlinear optical materials. J. Mater. Chem. 2010, 20, 2965–2971. https://doi.org/10.1039/B923616C
  82. Espinet P., Miguel J. A., Martín-Álvarez J. M., Villacampa B. Synthesis, crystal structure and second-order nonlinear optical properties of the trinuclear palladium orthomethalated complex [(μ3-S)( μ 3-OH)Pd3 (C^N) 3] (HC^N = p-Bu2n)–C6H4–CH=N–C6H4–NO2-p). J. Organometallic Chem. 2010, 695, 437-440. https://doi.org/10.1016/j.jorganchem.2009.10.028
  83. Alicante R., Cases R., Forcén P., Oriol L., Villacampa B. Synthesis and Nonlinear optical properties of Side Chain Liquid Crystalline Polymers containing Azobenzene Push-Pull Chromophores. J. Polym. Sci. A. Polym. Chem. 2010, 48, 232-242. https://doi.org/10.1002/pola.23776
  84. Rellán-Alvarez, R.; Giner-Martínez-Sierra, J.; Orduna, J.; Orera, I.; Rodríguez-Castrillón, J. A.; García-Alonso, J. I.; Abadía, J.; Alvarez-Fernández, A., Identification of a tri-iron(III), tri-citrate complex in the xylem sap of iron-deficient tomato resupplied with iron: New insights into plant iron long-distance transport. Plant Cell Physiol. 2010, 51, 91-102. https://doi.org/10.1093/pcp/pcp170
  85. Orera, I.; Orduna, J.; Abadía, J.; Alvarez-Fernández, A., Electrospray ionization collision-induced dissociation mass spectrometry: a tool to characterize synthetic polyaminocarboxylate ferric chelates used as fertilizers. Rapid Commun. Mass Spectrom. 2010, 24, 109-119. https://doi.org/10.1002/rcm.4361
  86. Juárez, R.; Ramos, M.; Segura, J. L.; Orduna, J.; Villacampa, B.; Alicante, R., Synthesis and Electrochemical and Theoretical Studies of V-Shaped Donor-Acceptor Hexaazatriphenylene Derivatives for Second Harmonic Generation. J. Org. Chem. 2010, 75, 7542-7549. https://doi.org/10.1021/jo101311v
  87. Coe, B. J.; Foxon, S. P.; Harper, E. C.; Helliwell, M.; Raftery, J.; Swanson, C. A.; Brunschwig, B. S.; Clays, K.; Franz, E.; Garín, J.; Orduna, J.; Horton, P. N.; Hursthouse, M. B., Evolution of Linear Absorption and Nonlinear Optical Properties in V-Shaped Ruthenium(II)-Based Chromophores. J. Am. Chem. Soc. 2010, 132, 1706-1723. https://doi.org/10.1021/ja908667p
  88. Coe, B. J.; Fielden, J.; Foxon, S. P.; Harris, J. A.; Helliwell, M.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Garín, J.; Orduna, J. Diquat Derivatives: Highly Active, Two-Dimensional Nonlinear Optical Chromophores with Potential Redox Switchability. J. Am. Chem. Soc. 2010, 132, 10498-10512. https://doi.org/10.1021/ja103289a
  89. Andreu, R.; Galán, E.; Garín, J.; Orduna, J.; Alicante, R.; Villacampa, B. Benzothiazolium-π-thiazole-dicyanomethanides: new nonlinear optical chromophores. Tetrahedron Lett. 2010, 51, 6863-6866. https://doi.org/10.1016/j.tetlet.2010.10.103
  90. Andreu, R.; Galán, E.; Garín, J.; Herrero, V.; Lacarra, E.; Orduna, J.; Alicante, R.; Villacampa, B. Linear and V-shaped nonlinear optical chromophores with multiple 4H-pyran-4-ylidene moieties. J. Org. Chem. 2010, 75, 1684-1692. https://doi.org/10.1021/jo902670z
  91. Andreu, R.; Franco, S.; Galán, E.; Garín, J.; Martínez de Baroja, N.; Momblona, C.; Orduna, J.; Alicante, R.; Villacampa, B. Isophorone- and pyran-containing NLO-chromophores: a comparative study. Tetrahedron Lett. 2010, 51, 3662-3665. https://doi.org/10.1016/j.tetlet.2010.05.033
  92. Font-Sanchís, E.; Cespedes-Guirao, F. J.; Sastre-Santos, A.; Villacampa, B.; Orduna, J.; Alicante, R.; Fernández-Lázaro, F. Synthesis and nonlinear optical properties of chromophores for photorefractive polymer materials. Tetrahedron 2009, 65, 4513-4520. https://doi.org/10.1016/j.tet.2009.03.099
  93. Andreu, R.; Carrasquer, L.; Garín, J.; Modrego, M. J.; Orduna, J.; Alicante, R.; Villacampa, B.; Allain, M. New one- and two-dimensional 4H-pyranylidene NLO-phores. Tetrahedron Lett. 2009, 50, 2920-2924. https://doi.org/10.1016/j.tetlet.2009.03.197
  94. Andreu, R.; Carrasquer, L.; Franco, S.; Garín, J.; Orduna, J.; Martínez de Baroja, N.; Alicante, R.; Villacampa, B.; Allain, M., 4H-Pyran-4-ylidenes: strong proaromatic donors for organic nonlinear optical chromophores. J. Org. Chem. 2009, 74, 6647-6657. https://doi.org/10.1021/jo901142f
  95. Ruiz Delgado, M. C.; Casado, J.; Hernández, V.; López Navarrete, J. T.; Orduna, J.; Villacampa, B.; Alicante, R.; Raimundo, J.-M.; Blanchard, P.; Roncali, J. Electronic, Optical, and Vibrational Properties of Bridged Dithienylethylene-Based NLO Chromophores. J. Phys. Chem. C 2008, 112, 3109-3120. https://doi.org/10.1021/jp710459c
  96. Andreu, R.; Cerdán, M. A.; Franco, S.; Garín, J.; Marco, A. B.; Orduna, J.; Palomas, D.; Villacampa, B.; Alicante, R.; Allain, M. Decreased Optical Nonlinearities upon CF3 Substitution on Tricyanofuran Acceptors. Org. Lett. 2008, 10, 4963-4966. https://doi.org/10.1021/ol802045a
  97. Alías, S.; Andreu, R.; Blesa, M. J.; Cerdán, M. A.; Franco, S.; Garín, J.; López, C.; Orduna, J.; Sanz, J.; Alicante, R.; Villacampa, B.; Allain, M., Iminium Salts of ω-Dithiafulvenylpolyenals: An Easy Entry to the Corresponding Aldehydes and Doubly Proaromatic Nonlinear Optic-phores. J. Org. Chem. 2008, 73, 5890-5898. https://doi.org/10.1021/jo800801q
  98. Alcalá R., Giménez R., Oriol L., Piñol M., Serrano J.L., Villacampa B., Viñuales A.I. Synthesis, Characterization and Induction of Stable Anisotropy in Liquid Crystalline Photo-addressable PPI Dendrimers. Chem. Mater. 2007, 19, 235-246. https://doi.org/10.1021/cm061727a
  99. Ruiz Delgado, M. C.; Orduna, J.; Moreno Oliva, M.; Casado, J.; López Navarrete, J. T. Theoretical understanding of the increment of β upon protonation of pyridine peripheral octupolar molecules: Toward nonlinear optical sensors. J. Chem. Phys. 2007, 127, 164704. https://doi.org/10.1063/1.2796167
  100. Ruiz Delgado, M. C.; Casado, J.; Hernández, V.; López Navarrete, J. T.; Kim, O.-K.; Woo, H. Y.; Villacampa, B.; Alicante, R.; Orduna, J.; Garín, J. NLO properties of dithienothiophene-based chromophores: a comparison study between the donor/donor and donor/acceptor substitution patterns. Proc. SPIE-Int. Soc. Opt. Eng. 2007, 6653, 66530X. https://doi.org/10.1117/12.733723
  101. Oswald, F.; Chopin, S.; de la Cruz, P.; Orduna, J.; Garín, J.; Sandanayaka, A. S. D.; Araki, Y.; Ito, O.; Delgado, J. L.; Cousseau, J.; Langa, F. Through-space communication in a TTF-C60-TTF triad. New J. Chem. 2007, 31, 230-236. https://doi.org/10.1039/B613466A
  102. Moreno Oliva, M.; Casado, J.; López Navarrete, J. T.; Hennrich, G.; Ruiz Delgado, M. C.; Orduna, J. Linear and Nonlinear Optical Properties of Pyridine-Based Octopolar Chromophores Designed for Chemical Sensing. Joint Spectroscopic and Theoretical Study. J. Phys. Chem. C 2007, 111, 18778-18784. https://doi.org/10.1021/jp076066z
  103. Casado, J.; Moreno Oliva, M.; Ruiz Delgado, M. C.; López Navarrete, J. T.; Sanchez, L.; Martín, N.; Andreu, R.; Carrasquer, L.; Garín, J.; Orduna, J., Vibrational fingerprint of the structural tuning in push-pull organic chromophores with quinoid or proaromatic spacers. J. Chem. Phys. 2007, 126 (7): 074701. https://doi.org/10.1063/1.2395936
  104. Andreu, R.; Carrasquer, L.; Cerdán, M. A.; Fernández, A.; Franco, S.; Garín, J.; Orduna, J. A simple synthesis of 2-methyl-1,3-dithiolium and related cations. Synlett 2007, 1470-1472. https://10.1055/s-2007-980362
  105. Alías, S.; Andreu, R.; Cerdán, M. A.; Franco, S.; Garín, J.; Orduna, J.; Romero, P.; Villacampa, B., Synthesis, characterization and optical properties of merocyanines derived from malononitrile dimer. Tetrahedron Lett. 2007, 48, 6539-6542. https://doi.org/10.1016/j.tetlet.2007.07.048
  106. Alías, S.; Andreu, R.; Blesa, M. J.; Franco, S.; Garín, J.; Gragera, A.; Orduna, J.; Romero, P.; Villacampa, B.; Allain, M. Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores. J. Org. Chem. 2007, 72, 6440-6446. https://doi.org/10.1021/jo070694v
  107. M.-J. Blesa, B.-T. Zhao, M. Allain, F. Le Derf, M. Sallé. Bis(calixcrown)tetrathiafulvalene Receptors. Chem. Eur. J., 2006, 12, 1906, 1914. https://doi.org/10.1002/chem.200500878
  108. Tejedor R.M., Millaruelo M., Oriol L., Serrano J.L., Alcalá R., Rodríguez F.J., Villacampa B. Photoinduced supramolecular chirality in side-chain liquid crystalline azopolymers. J. Mater. Chem. 2006, 16, 1674-1680. https://doi.org/10.1039/B518269G
  109. Rodríguez F.J., Sánchez C., Villacampa B., Alcalá R., Cases R., Millaruelo M., Oriol L., Lörincz E. Red light induced holographic storage in an azobenzene polymethacrylate at room temperature. Optical Materials, 2006, 28, 480-487. https://doi.org/10.1016/j.optmat.2005.02.005
  110. Oviedo, J. J.; El-Khouly, M. E.; de la Cruz, P.; Pérez, L.; Garín, J.; Orduna, J.; Araki, Y.; Langa, F.; Ito, O., Synthesis and photophysical properties of ruthenocene-[60]fullerene dyads. New J. Chem. 2006, 30, 93-101. https://doi.org/10.1039/B509221C
  111. Coe, B. J.; Harris, J. A.; Hall, J. J.; Brunschwig, B. S.; Hung, S.-T.; Libaers, W.; Clays, K.; Coles, S. J.; Horton, P. N.; Light, M. E.; Hursthouse, M. B.; Garín, J.; Orduna, J., Syntheses and Quadratic Nonlinear Optical Properties of Salts Containing Benzothiazolium Electron-Acceptor Groups. Chem. Mater. 2006, 18, 5907-5918. https://doi.org/10.1021/cm061594t
  112. Coe, B. J.; Harries, J. L.; Helliwell, M.; Jones, L. A.; Asselberghs, I.; Clays, K.; Brunschwig, B. S.; Harris, J. A.; Garín, J.; Orduna, J., Pentacyanoiron(II) as an Electron Donor Group for Nonlinear Optics: Medium-Responsive Properties and Comparisons with Related Pentaammineruthenium(II) Complexes. J. Am. Chem. Soc. 2006, 128, 12192-12204. https://doi.org/10.1021/ja063449m
  113. Casado, J.; Delgado, M. C. R.; Merchán, M. C. R.; Hernández, V.; López Navarrete, J. T. ; Pappenfus, T. M.; Williams, N.; Stegner, W. J.; Johnson, J. C.; Edlund, B. A.; Janzen, D. E.; Mann, K. R.; Orduna, J.; Villacampa, B., Optical, redox, and NLO properties of tricyanovinyl oligothiophenes: comparisons between symmetric and asymmetric substitution patterns. Chem.Eur. J. 2006, 12, 5458-5470. https://doi.org/10.1002/chem.200501389
  114. Andreu, R.; Aramburo, J.; Cerdán, M. A.; Garín, J.; Orduna, J.; Villacampa, B., Highly polarized dithiafulvenes: synthesis and nonlinear optical properties. Tetrahedron Lett. 2006, 47, 661-664. https://doi.org/10.1016/j.tetlet.2005.11.112

Scroll to Top